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Relation between canonical and ensemble

The inverse Burnett coefficients are defined in terms of the derivatives with respect to the flux of the average of a thermodynamic force in an ensemble where the flux is fixed value. In this section, we demonstrate the equivalence of this and derivatives with respect to the flux in a canonical ensemble. The subset of the canonical ensemble in which the   flux takes on a specific value of J is called the -ensemble. One may write a phase average <B> as an integration over all possible -ensembles  

 

where is the probability that the flux takes on a specific value J, and is the phase average in the -ensemble.

In the thermodynamic limit, will be clustered about with infinitesimal spread, suggesting that we can write a Taylor series expansion of about :

Substituting this into (gif), we find that

From Appendix gif, is of order in the large system limit, and so it is clear that the ensemble corrections are of order .



Russell Standish
Thu May 18 11:43:52 EST 1995