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Conventional Theories

In the previous chapters, I have developed a theory on the form of non-hydrodynamic effects in time of flight experiments. The    obvious extension to this work is to develop such a theory for the other main classes of swarm experiments, namely the Steady State Townsend experiments and the Pulsed Townsend experiment.    In this chapter, I develop a theory of the parallel plane experiment. The generalization to the Townsend-Huxley experiment, involving as it does elements of multivariable complex analysis, is not straightforward, and so little will be said in this case.

In the conventional theory of steady state experiments, the diffusion equation (gif) is   solved with the time derivative set to zero. The homogeneous equation gives rise to solutions in terms of modified Bessel functions of half integer   order, which are merely polynomials in the inverse distance from the source, multiplied by an exponential of this distance. At large distances, the dominant term from a compact source is , where and . For a planar source, as in the parallel plane experiment, the dominant term is , which as noted in the previous section, is seen experimentally. The remaining terms, in the case of a compact source, arise from the structure of the source. These decay polynomially with respect to the dominant mode, away from the source. Since these effects are clustered near the source, a full theory should also include a description of the relaxation to local thermal equilibrium of the particles as they leave the source. This requires a theory based on the Boltzmann equation.  

The usual technique for analysing the parallel plane experiment by means of the Boltzmann equation was first developed by Thomas [1969], and subsequently used by many authors. This involves assuming the solution has an exponential dependence on distance. The Boltzmann equation with one spatial dimension is solved by solutions of the form

 

where the are the roots of , where r indexes the roots of . It might be supposed that only solutions (gif) are needed for the general solution:

 

Since it is known experimentally that the distribution function varies exponentially as a function of the distance from the source, one might assume that there is a root whose real part is larger than all the others, and so contributes dominantly to the distribution function at large distances from the source. If this is the case, then we can identify this root with .

For the one dimensional Klein-Kramers model, one can readily   solve from the one dimensional version of (gif). In the following, we will use dimensionless units, in which and . In these units, the mean free time of the charged particle is and the mean free path is . From the usual quadratic formula, the roots of are easily found to be

 

The first Townsend ionization coefficient   can be identified with the largest root of the negative branch . [Blevin and Fletcher [1984]]

There are an infinite number of positive branch roots that one would expect to dominate over the term in (gif), and so (gif) does not in this case agree with what one expects to see physically. This raises the question of why only the negative branch roots contribute to the solution, and of what role the positive branch roots play. To get some insight into the problem, the number density was computed numerically for the Klein-Kramers model. This work has been reported as Standish [1989].



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Russell Standish
Thu May 18 11:43:52 EST 1995